Aquachlorido(4-methylbenzoato-κO)(1,10-phenanthroline-κ2 N,N′)copper(II)
نویسندگان
چکیده
In the title mononuclear complex, [Cu(C(8)H(7)O(2))Cl(C(12)H(8)N(2))(H(2)O)], the Cu(II) atom is coordinated by one carboxylate O atom from a monodentate 4-methyl-benzoate ligand, two N atoms from the 1,10-phenanthroline ligand, one chloride ion and one water mol-ecule in a square-pyramidal geometry. The crystal structure exhibits inter- and intra-molecular C-H⋯Cl, C-H⋯O, O-H⋯Cl and O-H⋯O hydrogen bonds, as well as C-H⋯π inter-actions of phenanthroline and methyl H atoms towards the π-systems of neighboring 4-methyl-benzoate units and the pyridine rings of the phenanthroline system [centroid-centroid distances are 2.706 (2) and 2.992 (1) Å, respectively].
منابع مشابه
μ-Aqua-bis(μ-4-methylbenzoato-κ2 O:O′)bis[(4-methylbenzoato-κO)(1,10-phenanthroline-κ2 N,N′)iron(II)]
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008